Luminescence and ESR dating of the sedimentary infill from the multi-level cave system of Alkerdi-Zelaieta (Navarre,N Spain)     

《Quaternary Geochronology》2022

The finding of Upper Paleolithic engravings in 2016 triggered a multidisciplinary investigation of the Alkerdi cave system (Urdazubi, N Spain). The study of the speleogenetic processes led to the identification of at least 6 paragenetic cave levels with associated sedimentary infill. In order to unravel the timing of changes in the karst dynamics and to get some insights about sediment origin, two sediment samples were collected from cave levels 4 and 1 for numerical dating purpose, using both Optically Stimulated Luminescence (OSL) and Electron Spin Resonance (ESR) methods. One additional modern-age sample was also taken from the entrance of the karst to evaluate the magnitude of the optical bleaching achieved by the quartz grains before entering the cave system. Last, one sample was collected from a flowstone for U-series dating, providing independent age control.OSL measurements were carried out using small quartz multi-grain (MG) and single-grain (SG) Single Aliquot Regenerative-dose (SAR) protocol. Initial Equivalent Dose (D_e) results show evidence of saturated OSL signal for the sample of the higher level (with ∼60% of saturated aliquots). Unlike SA data, SG analyses do not meet the usual quality criteria (e.g., relatively high recuperation ratios, only a few grains with useable signal), suggesting that corresponding dating results should be treated with caution.Hence, both MG and SG TT-OSL and MG ESR methods were subsequently employed, as the corresponding signals are known to have higher saturation levels than OSL ones. ESR analyses were based on the Multiple Centre (MC) approach using the standard multi-grain multi-aliquot additive (MAA) dose method, while TT-OSL measurements were performed following Demuro et al. (2020). The latter, however, did not return any useful results for both samples. MC ESR data show the usual D_e pattern (D_e(Al)>D_e(Ti op. D)>D_e(Ti–H)) indicating that among the three ESR signals analyzed, the Ti–H most likely provides the closest estimate to the true burial age. However, low measurement repeatability and goodness-of-of fit indicate that the reliability of the ESR results may be reasonably questioned.Results derived from this multi-technique dating approach provide the first chronological constraints for the sedimentary infill of the Alkerdi cave system. In particular, they suggest that sediment deposition in Cave Level 4 (ALK-OSL01) occurred around 130 ka, which is in good agreement with the minimum age constraint given by the speleothem (80.5 ± 9.0 ka). In comparison, the young age obtained for sample ALK-OSL02 (5.0 ± 0.9 ka) suggests recent Holocene formation of the lowest cave level 1.Finally, the MG De value obtained for the modern sample is close to zero (<1 Gy), indicating that the OSL signal is almost fully reset at a multi-grain level before entering the cave. Additionally, despite the large De overdispersion measured in this modern sample, the De values are one to two order of magnitude lower than those obtained with the same model in the other two samples. Therefore, the large OSL D_e overdispersion (OD) values of up to 64% obtained for the two samples from Cave Level 4 and 1 are most likely related to re-sedimentation processes inside the cave system.  相似文献   

Testing a new combined (U,Th)–He and U/Th dating approach on Plio-Pleistocene calcite speleothems     

《Quaternary Geochronology》2022

The geochronology of cave deposits in the Cradle of Humankind UNESCO World Heritage Site in South Africa provides a timeframe essential for the interpretation of its fossils. The uranium-lead (U–Pb) and uranium-thorium disequilibrium (U/Th) dating of speleothems, mostly flowstones that underlie and blanket the fossil-bearing sediments, have been effective in this sense, but U–Pb is limited by the requirement of ∼1 ppm U concentrations and low common Pb contents, and U/Th has a c. 500 ka limit of applicability. Here we report age results for calcite-aragonite speleothems obtained using a new combined uranium-thorium-helium ((U,Th)–He) and U/Th dating routine. We reproduced within analytical uncertainty, the published U–Pb or U/Th ages for (a) flowstone in three drill core samples in the range 2000–3000 ka, (b) a flowstone hand sample taken at surface with an age of 1800 ka, and (c) five underground flowstone samples in the range 100–800 ka. Calcite retentivity for He under cave conditions is thus demonstrated. In the few cases where helium loss was observed in speleothems, only some of the subsamples were affected, and to varying degrees, suggesting loss by lattice damage not related to diagenetic processes, rather than volume diffusion. In the 100 to 800 ka range, the combined U/Th disequilibrium and (U,Th)–He method also yielded reliable values for initial (²³⁰Th/²³⁸U) and (²³⁴U/²³⁸U) activity ratios. Importantly, most subsamples had high initial (²³⁰Th/²³⁸U) values, ranging from 1.0 to 19.7, although having low Th/U ratios. This is probably due to incorporation of Fe–Mn oxides-hydroxides dust, on which ²³⁰Th was previously adsorbed. Such samples are mostly not dateable by U/Th without the additional input from the He analysis. If not detected and corrected for, such high initial (²³⁰Th/²³⁸U) values can lead to inaccurate U/Th and U–Pb ages. Our study shows that the incorporation of He analysis in U/Th dating has broad potential application, with four methods for calculating the ages, in carbonates from different environments where U-Pb or U/Th dating would not work.  相似文献   

Isolating quartz-dominated OSL signal of rock slice by using pulsed stimulation: Implications for dating burial age of cobbles     

《Quaternary Geochronology》2022

Although the OSL signal sourced from quartz is expected to be more stable and bleached more rapidly than the IRSL signal sourced from feldspar in a general sense, the former is much less investigated than the latter for rock surface related luminescence dating. It is mainly due to the difficulty in isolating quartz-dominated OSL signals from rock slices, and the low sensitivity and non-fast component dominated OSL signals for quartz in most of rocks. In merit of the sub-conduction band transition of trapped electrons of feldspar under both green light stimulation and IR stimulation at elevated temperature (Jain and Ankjӕrgaard, 2011), it is expected that the contribution of feldspars to the green light stimulated luminescence could be substantially reduced by a prior IR stimulation at elevated temperature. Meanwhile, more fast-component dominated quartz OSL signal (if there is any) could be obtained by green light stimulation (Bailey et al., 2011). Therefore, in this study, we investigated the feasibility of using the post-IR pulsed green stimulation, which is performed at 25 °C (PGLSL₂₅) following two IR stimulations (IR₅₀IR₂₂₅), to isolate the quartz-dominated OSL signals from rock slices of granite cobbles for burial dating. The decay characteristics of stimulation curve, characteristic saturation dose and thermal stability of the pIR₅₀IR₂₂₅ PGLSL₂₅ signal suggest that this signal is quartz-dominated, but still not fast-component dominated. We tentatively validated the equivalent dose (D_e) measurement protocol by dose recovery experiment. The luminescence-depth profiles show that the bleaching depths of pIR₅₀IR₂₂₅ PGLSL₂₅ signals are slightly smaller than or close to that of the IR₅₀ signals, while they are much shallower for the pIR₅₀IR₂₂₅ signals. The pIR₅₀IR₂₂₅ PGLSL₂₅ procedure enables multiple D_e values determined from luminescence signals, with different bleachabilities and stabilities, from both feldspars and quartz in one measurement, which is of potential for buried age dating of cobbles.  相似文献   

A method to evaluate the degree of bleaching of IRSL signals in feldspar: The 3ET method     

《Quaternary Geochronology》2022

In addition to dating, IRSL luminescence signals can preserve information about erosional, transport, and depositional histories of a population of grains. Knowledge of the degree of bleaching can be useful in understanding the processes that occurred during previous depositional events, as certain transport conditions result in a well bleached signal, while others result in grains retaining an inherited signal from prior events. This information can be accessed by making single-grain IRSL measurements across successively increasing temperatures, thereby isolating signals from traps of different bleachabilities.A new approach offers a way to evaluate the completeness of bleaching of a grain by testing patterns of equivalent dose (D_E) values measured at three elevated temperatures (3ET), 50, 125, and 225 °C. Consistent D_E estimates across two or more temperatures suggest a single bleaching event of sufficient duration to fully depopulate the traps involved. Incompletely bleached grains with inconsistent D_E values across temperatures will lack a 3ET “plateau.” Modes in the distribution of D_E values for fully bleached grains can suggest depositional ages, subject to assessment of fading. We developed a Python code in a Jupyter Notebook environment for data analysis and visualization to expedite processing the large data sets produced by the 3ET protocol.The 3ET protocol was tested on a radiocarbon dated sequence of playa samples from California, USA and on a set of fluvial terraces in the Marlborough region of New Zealand as part of a larger project to reconstruct regional seismic history. Where standard pIRIR apparent ages can be inconsistent or ambiguous, 3ET age estimates produce generally consistent apparent ages. Modes of 3ET plateaus can be used to infer the most recent and prior events that resulted in a sub-population of grains being fully bleached. These initial results suggest that the 3ET method can be useful to characterize both the age and degree of bleaching of depositional events.  相似文献   

Rapid assessment of beta dose variation inside cobbles,and implications for rock luminescence dating     

《Quaternary Geochronology》2022

Variation in beta dose rate within rocks may impact the results of rock surface luminescence dating, for both the burial age of cobbles and exposure age of rock surfaces. Current methods of rock surface luminescence dating assume that radionuclides are homogeneously distributed inside rocks. In this study, two rapid methods based on beta counting and on a portable XRF instrument were developed to measure the radioactivity of rock slices. These methods were applied to rock slices from four glaciofluvial granite cobbles that had previously been used for equivalent dose determination to test whether beta dose variation could be observed. Results from beta counting and K content from XRF show similar patterns and both vary along the depth profiles, but the magnitude of this variability is very different amongst the four cobbles. In rocks where the dose rate is highly variable, bleaching may not be the only source of variation of L_n/T_n or equivalent dose (D_e) along the luminescence-depth profile of cobbles, and it may be necessary to measure the beta dose rate for every single slice to determine whether multiple bleaching events are recorded or variations in D_e are due to dose rate heterogeneity.  相似文献   

Luminescence dating reveals a rapid response to climate change of fluvial terrace formation along the Ani River,northeastern Japan,during the last glacial period     

《Quaternary Geochronology》2022

Fluvial terraces along the middle reaches of many Japanese rivers were formed during the last glacial period as a result of changes in sediment discharge related to cooler temperatures and/or reduced water discharge because of lower precipitation. The influence of climate change on these fluvial terraces is not yet fully understood because most previous studies lacked detailed reconstructions of the chronology of terrace development. This study provides a detailed luminescence chronology of fluvial terrace deposits along the Ani River, northeastern Honshu, Japan, and compares that chronology to paleoclimatic records. Eight samples for luminescence dating were obtained from an outcrop of terrace deposits (∼10 m thick) in the Ani River valley. The fading-corrected infrared stimulated luminescence (IRSL) ages are consistent with the fading-corrected post-IR IRSL ages for some samples, which suggests that fading corrections were effective despite the higher fading rates of the IRSL signal. However, for the other samples, the post-IR IRSL ages are significantly older than the fading-corrected IRSL ages due to incomplete bleaching. The pulsed IRSL signals are close to field saturation for older samples, which might have resulted in a greater variation of the ages. Fading-corrected IRSL ages demonstrate periods of rapid aggradation during 105–90 ka and 75–60 ka. Comparison of terrace development with paleoclimatic records indicates that the two periods of fluvial deposition correspond to decreases in precipitation caused by weakened East Asian summer monsoon precipitation and possibly decreases in temperature. The results of this study show that the Ani River responded rapidly to climate change on a time scale of a few tens of thousands of years during the last glacial period.  相似文献   

粤东铁坑坳铁锡多金属矿床锆石及锡石U-Pb年代学、Nd-Hf同位素特征及其意义     

张志涛  柯昌辉  徐林刚  马收先  陈懋弘  叶会寿  潘玉峰 《矿床地质》2022,41(3):543-566

铁坑坳铁锡多金属矿床位于粤东莲花山断裂带西部,矿区出露的花岗岩类主要有粗粒二长花岗岩和花岗闪长斑岩,花岗质岩石与碳酸盐岩的接触带中发育铁锡多金属矿化。该矿区的成岩成矿时代尚不明确,成矿与哪一种岩体具有成因上的联系也不清楚。文章选择与铁锡多金属矿体相关的花岗岩类的锆石和块状矿石中的锡石,首次开展LA-ICP-MS U-Pb定年和Nd-Hf同位素研究。结果表明：粗粒二长花岗岩和花岗闪长斑岩的锆石U-Pb年龄分别为（132±1） Ma （n=24,MSWD=0.78）和（94±1） Ma （n=25,MSWD=1.80）;块状矿石中锡石U-Pb年龄为（130±3） Ma （n=36,MSWD=0.62）,成矿时代与粗粒二长花岗岩形成时代基本一致,均形成于早白垩世;粗粒二长花岗岩的锆石ε_Hf （t）变化于-4.9~-0.1,平均值为-2.8,地壳Hf模式年龄T_DMC=1192~1497 Ma,平均值为1366 Ma,全岩ε_Nd （t）值介于-8.8~-8.7,Nd同位素二阶段模式年龄T_DM2变化于1630~1642 Ma;花岗闪长斑岩的锆石ε_Hf （t）变化于-5.7~-2.9,平均值为-4.4,地壳Hf模式年龄T_DMC=1342~1523 Ma,平均值为1440 Ma,全岩ε_Nd （t）值介于-5.4~-4.9,Nd同位素二阶段模式年龄T_DM2变化于1291~1332 Ma。Nd-Hf同位素综合研究表明,粗粒二长花岗岩的源区物质主要来自于中元古代地壳,有少量幔源组分或新生地壳的加入,花岗闪长斑岩的源区物质中幔源组分或新生地壳的混入比例高于粗粒二长花岗岩。  相似文献   

锆石辐射损伤测年方法研究进展与应用     

范明璞  柳小明  孙圣思 《地质论评》2022,68(5):2022102003-2022102003

锆石辐射损伤测年是一种新兴的低温热年代学方法（封闭温度为~230 ± 25 ℃）,其原理是依据拉曼半高宽（ν3）计算出锆石所累积的α通量,结合U、Th含量,得出锆石辐射损伤的累积时间,即锆石辐射损伤年龄。相较于其他低温年代学方法,锆石辐射损伤测年具有测试简便、高效、低成本、双（多）定年等优势,在地学研究中展现出广泛的应用前景,现已成功应用于示踪物源区和揭示岩体热事件等领域。然而,该方法尚存几个关键问题有待解决,例如,微区测试的空间不匹配性、封闭温度存有争议、较大的年龄偏差等,这无疑阻碍其在地球科学领域中更进一步的推广和应用。本文系统地介绍了锆石辐射损伤测年方法的起源、原理和测试方法,总结了相关应用的重要进展,阐述了锆石辐射损伤测年方法的尚存问题,并对该方法的发展趋势作以展望,以期为年代学的发展提供新的技术手段。  相似文献   

胶东半岛乳山地区低角度韧性剪切带几何学、运动学特征:对中国东部岩石圈减薄作用的启示     

郝志宣  金超  田忠华  李同宇  文飞 《地质科学》2022,57(1):43-60

大规模伸展构造是华北克拉通东部岩石圈减薄的重要表现形式。部分低角度韧性剪切带是地壳伸展变形后所展现的构造形式。本文研究了王格庄韧性剪切带的岩石学、几何学、运动学等特征显示:韧性剪切带走向近南北向,剪切带断层面倾向多变(倾向西、西南、西北方向)。大部分区域面理低角度倾向西,矿物拉伸线理近东西向,不对称旋转碎斑及S-C组构指示顶端指向西的剪切特征。结合研究区西侧与伸展构造相匹配的半地堑伸展盆地证据:本研究认为伸展构造的形成可能与西太平洋板块的后撤相关,即大规模伸展构造作用引发了华北克拉通东部的地壳减薄作用。  相似文献   

若尔盖黄河唐克段河岸沉积序列测年及地表过程变化     

周家和  周亚利  黄春长  查小春  庞奖励  张玉柱  尚瑞清 《冰川冻土》2022,44(4):1188-1202

通过对若尔盖盆地进行野外考察,在盆地中部黄河唐克段右岸发现了包含深湖相的河岸沉积物,进行了细致的地层观测和系统年代学样品采集。在实验室利用光释光和AMS¹⁴C测年技术建立了年代框架,并结合各个层次的地层沉积相宏观特征和理化性质,分析探讨了若尔盖盆地内部从末次冰期古湖消亡以来的环境和地表过程变化规律。研究结果表明：古黄河在37 ka沿着玛曲断陷谷地溯源侵蚀,沟通了若尔盖古湖水系,盆地内部在30.9 ka之前为深湖环境,稳定地沉积了蓝灰色湖相淤泥层。30.9 ka之后,黄河贯穿若尔盖湖盆内部,古湖水外泄消失,原有的古湖水系转变成为黄河源水系。黄河从湖盆上游远距离搬运携带来的浊黄橙色泥沙大量沉积,覆盖了古湖相沉积层,湖盆内部风沙作用盛行。在末次冰盛期（Last Glacial Maximum, LGM）,盆地内部松散沉积物普遍地受到冰缘冻融作用的改造,形成了冻融褶皱现象。到了14.6~12.5 ka,响应B/A（B?lling-Aller?d）时期的温暖气候,盆地周边山地冰川消融,冰融水汇入盆地,古湖盆底部各种浅洼地形成了大小不等的浅湖,沉积了滨浅湖相的沙层。在12.5~11.7 ka,对应于全球性新仙女木（Younger Dryas,YD）事件,盆地气候再次变冷,转变为冰缘冻土环境,盆地内部滨浅湖相的沙层受到冻融作用和古地震扰动,形成复式褶皱现象。进入全新世,在11.7~4.8 ka气候逐渐变得温暖湿润,古湖盆底部浅洼地积水成为淤泥质沼泽环境,在全新世中后期4.8~1.8 ka则转变成为沼泽草甸环境,在1.8 ka之后,盆地内沼泽面积收缩,风沙活动盛行,河岸台地的近源沙尘暴沉积物经过成壤改造形成亚高山草甸黑土类现代土壤。  相似文献